Reactions of allylic carbonates catalyzed by palladium, rhodium, ruthenium, molybdenum, and nickel complexes; allylation of carbonucleophiles and decarboxylation- dehydrogenation

Ichiro Minami, Isao Shimizu, Jiro Tsuji

    研究成果: Article

    122 引用 (Scopus)

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    Allylation of carbonucleophiles with allylic carbonates catalyzed by various transition metal complexes has been studied. Palladium, rhodium, ruthenium, nickel, and molybdenum complexes were found to be active catalysts. The rhodium catalyst showed a different regioselectivity from the other catalysts, the reaction can proceed without allylic rearrangement. In the absence of nucleophiles, allyl alkyl carbonates were converted into ketones by decarboxylation-dehydrogenation; the ruthenium catalyst was the most active in this reaction.

    元の言語English
    ページ(範囲)269-280
    ページ数12
    ジャーナルJournal of Organometallic Chemistry
    296
    発行部数1-2
    DOI
    出版物ステータスPublished - 1985 11 26

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    ASJC Scopus subject areas

    • Biochemistry
    • Chemical Engineering (miscellaneous)
    • Inorganic Chemistry
    • Organic Chemistry
    • Physical and Theoretical Chemistry
    • Materials Science (miscellaneous)
    • Materials Chemistry

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