Reactions of allylic carbonates catalyzed by palladium, rhodium, ruthenium, molybdenum, and nickel complexes; allylation of carbonucleophiles and decarboxylation- dehydrogenation

Ichiro Minami, Isao Shimizu, Jiro Tsuji

    研究成果: Article査読

    125 被引用数 (Scopus)

    抄録

    Allylation of carbonucleophiles with allylic carbonates catalyzed by various transition metal complexes has been studied. Palladium, rhodium, ruthenium, nickel, and molybdenum complexes were found to be active catalysts. The rhodium catalyst showed a different regioselectivity from the other catalysts, the reaction can proceed without allylic rearrangement. In the absence of nucleophiles, allyl alkyl carbonates were converted into ketones by decarboxylation-dehydrogenation; the ruthenium catalyst was the most active in this reaction.

    本文言語English
    ページ(範囲)269-280
    ページ数12
    ジャーナルJournal of Organometallic Chemistry
    296
    1-2
    DOI
    出版ステータスPublished - 1985 11 26

    ASJC Scopus subject areas

    • 生化学
    • 化学工学(その他)
    • 無機化学
    • 有機化学
    • 物理化学および理論化学
    • 材料科学(その他)
    • 材料化学

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