抄録
Enantioselective cycloaddition using chiral transition metal catalysts is an atom-economical and efficient synthetic tool for the construction of chiral carbo- and heterocyclic skeletons. This short account discloses our recent results of inter- and intramolecular enantioselective [2 + 2 + 2] cycloadditions of alkyne and/or alkene moiety(ies). Chiral iridium complexes catalyzed the alkyne trimerization for the generation of axial chirality(ies), and chiral rhodium ones catalyzed alkyne-alkyne-alkene cyclization for the generation of a quaternary carbon including spirocyclic system.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 1317-1323 |
| ページ数 | 7 |
| ジャーナル | Organic and Biomolecular Chemistry |
| 巻 | 6 |
| 号 | 8 |
| DOI | |
| 出版ステータス | Published - 2008 4月 8 |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学