Recent Advances of Biphenylene: Synthesis, Reactions and Uses

Hideaki Takano, Takeharu Ito, Stephen Kyalo Kanyiva, Takanori Shibata

研究成果: Review article

抄録

Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.

元の言語English
ジャーナルEuropean Journal of Organic Chemistry
DOI
出版物ステータスPublished - 2019 1 1

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Functional materials
Organometallics
Benzene
musculoskeletal system
Ligands
Catalysts
Molecules
synthesis
butadiene
spacers
reactivity
benzene
catalysts
ligands
rings
molecules
1,3-butadiene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

これを引用

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abstract = "Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.",
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AU - Takano, Hideaki

AU - Ito, Takeharu

AU - Kanyiva, Stephen Kyalo

AU - Shibata, Takanori

PY - 2019/1/1

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N2 - Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.

AB - Biphenylene is an antiaromatic compound that has a strained butadiene skeleton that joins two benzene rings. Various methods for synthesizing the biphenylene core have been developed. In addition, the reactivity of biphenylene has attracted much attention because C–C bonds of biphenylene can be cleaved by various organometallic species. Furthermore, the biphenylene motif not only acts as a spacer in a variety of functional molecules, but also serves as a backbone for catalysts and ligands. This minireview summarizes how to construct the biphenylene structure, how to react biphenylene, and how to use the biphenylene skeleton in functional materials.

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