Poly(TEMPO-substituted norbornene) was synthesized by ring-opening metathesis polymerization by using Grubbs catalyst. The polymer was photo-crosslinked by bisazide or oxetane derivatives, and applied to an electrode-active material. The obtained radical thin film displayed a stable redox behavior at 3.6V vs. Li/Li+.The test cell was fabricated with the polymer cathode and lithium anode.No deterioration of the capacity was observed after 500 cycles.
|出版ステータス||Published - 2006 12 1|
|イベント||55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan|
継続期間: 2006 9 20 → 2006 9 22
|Other||55th Society of Polymer Science Japan Symposium on Macromolecules|
|Period||06/9/20 → 06/9/22|
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