抄録
The title reaction velocity was studied at 10-40°C under high pressure (up to 200 MPa) using a high-pressure stopped flow apparatus. The resultant activation volume (20-16 cm3 mol-1) depends on the reaction temperature. It increases with increasing temperature up to 15°C and then decreases with increasing temperature. The latter decrease is consistent with the concept of the mechanistic changeover at high temperature of the title reaction from the rate-determining chloride liberation to the rate-determining conjugate base formation of the reactant complex.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 2969-2970 |
| ページ数 | 2 |
| ジャーナル | Polyhedron |
| 巻 | 15 |
| 発行部数 | 17 |
| DOI | |
| 出版物ステータス | Published - 1996 6 |
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ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
これを引用
Reinvestigation of the activation volume for the base hydrolysis reaction of trans-dichloro [(RSSR)-1,4,8,11-tetraazacyclotetradecane] cobalt(III) cation. / Ishihara, Koji; Kitamura, Yoichi.
：: Polyhedron, 巻 15, 番号 17, 06.1996, p. 2969-2970.研究成果: Article
}
TY - JOUR
T1 - Reinvestigation of the activation volume for the base hydrolysis reaction of trans-dichloro [(RSSR)-1,4,8,11-tetraazacyclotetradecane] cobalt(III) cation
AU - Ishihara, Koji
AU - Kitamura, Yoichi
PY - 1996/6
Y1 - 1996/6
N2 - The title reaction velocity was studied at 10-40°C under high pressure (up to 200 MPa) using a high-pressure stopped flow apparatus. The resultant activation volume (20-16 cm3 mol-1) depends on the reaction temperature. It increases with increasing temperature up to 15°C and then decreases with increasing temperature. The latter decrease is consistent with the concept of the mechanistic changeover at high temperature of the title reaction from the rate-determining chloride liberation to the rate-determining conjugate base formation of the reactant complex.
AB - The title reaction velocity was studied at 10-40°C under high pressure (up to 200 MPa) using a high-pressure stopped flow apparatus. The resultant activation volume (20-16 cm3 mol-1) depends on the reaction temperature. It increases with increasing temperature up to 15°C and then decreases with increasing temperature. The latter decrease is consistent with the concept of the mechanistic changeover at high temperature of the title reaction from the rate-determining chloride liberation to the rate-determining conjugate base formation of the reactant complex.
UR - http://www.scopus.com/inward/record.url?scp=0041115812&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0041115812&partnerID=8YFLogxK
U2 - 10.1016/0277-5387(96)00091-5
DO - 10.1016/0277-5387(96)00091-5
M3 - Article
VL - 15
SP - 2969
EP - 2970
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 17
ER -