Rh-catalyzed cyclization of diynes and enynes initiated by carbonyl-directed activation of aromatic and vinylic C-H bonds

Kyoji Tsuchikama; Yusuke Kuwata; Yu Ki Tahara; Yusuke Yoshinami; Takanori Shibata

doi:10.1021/ol0711669

Rh-catalyzed cyclization of diynes and enynes initiated by carbonyl-directed activation of aromatic and vinylic C-H bonds

Kyoji Tsuchikama, Yusuke Kuwata, Yu Ki Tahara, Yusuke Yoshinami, Takanori Shibata

先進理工学部

研究成果: Article › 査読

59 被引用数 (Scopus)

抄録

The Rh-catalyzed hydroarylative and hydrovinylative cyclization of diynes with aryl ketones or enones gave monocyclic 1,3-dienes. Enynes also underwent the same reaction and chiral products were obtained with high ee using a chiral Rh catalyst. Carbonyl-directed activation of aromatic and vinylic C-H bonds is likely the initial step in the present transformation.

本文言語	English
ページ（範囲）	3097-3099
ページ数	3
ジャーナル	Organic Letters
巻	9
号	16
DOI	https://doi.org/10.1021/ol0711669
出版ステータス	Published - 2007 8 2

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

文献へのアクセス

10.1021/ol0711669

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引用スタイル

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AU - Shibata, Takanori

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