抄録
The Rh-catalyzed hydroarylative and hydrovinylative cyclization of diynes with aryl ketones or enones gave monocyclic 1,3-dienes. Enynes also underwent the same reaction and chiral products were obtained with high ee using a chiral Rh catalyst. Carbonyl-directed activation of aromatic and vinylic C-H bonds is likely the initial step in the present transformation.
本文言語 | English |
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ページ(範囲) | 3097-3099 |
ページ数 | 3 |
ジャーナル | Organic Letters |
巻 | 9 |
号 | 16 |
DOI | |
出版ステータス | Published - 2007 8 2 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry