Rheological behavior of shear-responsive metallo-supramolecular gels

Yiqiang Zhao, J. Benjamin Beck, Stuart J. Rowan, Alex M. Jamieson

研究成果: Article

104 引用 (Scopus)

抜粋

Rheological behavior of the metallo-supramolecular gels was analyzed. A metallosupramolecular gel, 1:Zn/La gel, used for the analysis was formed by sequential binding of monomer with 3 mol % La(III) nitrate followed by 97 mol % Zn(II) perchlorate and swollen in acetonitrile. It was observed that partial reconstitution of the network took place instantaneously, but complete regeneration of the preexisting gel took approximately 18 minutes. The results show that the storage modulus remains constant but the yield stress and strain increase linearly, after the initial formation of a loose gel.

元の言語English
ページ(範囲)3529-3531
ページ数3
ジャーナルMacromolecules
37
発行部数10
DOI
出版物ステータスPublished - 2004 5 18
外部発表Yes

ASJC Scopus subject areas

  • Materials Chemistry

フィンガープリント Rheological behavior of shear-responsive metallo-supramolecular gels' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Zhao, Y., Beck, J. B., Rowan, S. J., & Jamieson, A. M. (2004). Rheological behavior of shear-responsive metallo-supramolecular gels. Macromolecules, 37(10), 3529-3531. https://doi.org/10.1021/ma0497005