Rhodium(I)-catalyzed reactions via carbon-hydrogen bond cleavage

Takanori Shibata*

*この研究の対応する著者

研究成果: Chapter

抄録

This chapter focuses on Rh(I)-catalyzed synthetic transformations initiated by carbon-hydrogen (C-H) bond cleavage. The Ru-catalyzed carbonyl-directed C-H alkylation by alkenes is a monumental achievement in organic chemistry. In this reaction, a nitrogen-containing moiety was commonly used as an efficient directing group. Alkynes are conventional coupling partners in C-H activation and alkenylated products are obtained with perfect atom economy. C-H bond cleavage along with carbon-carbon bond-forming reactions provides synthetically useful compounds in one pot. While the metalation of organohalides and subsequent reaction with trialkyl borate is a conventional protocol for the preparation of organoboron compounds, C-H borylation is a more direct and atom-economical approach. Aryl and alkyl silanes are synthetically important because they are functional molecules in themselves and are useful intermediates for further transformations. Among the various approaches to the synthesis of silane-containing compounds, dehydrogenative C-H/Si-H coupling is an atom-economical protocol.

本文言語English
ホスト出版物のタイトルRhodium Catalysis in Organic Synthesis
ホスト出版物のサブタイトルMethods and Reactions
出版社wiley
ページ277-297
ページ数21
ISBN(電子版)9783527811878
ISBN(印刷版)9783527343645
DOI
出版ステータスPublished - 2018 12 28

ASJC Scopus subject areas

  • 化学 (全般)

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