Ring-opening metathesis polymerization as a route to controlled copolymers of ethylene and polar monomers: Synthesis of ethylene-vinyl chloride-like copolymers

Hongli Yang, Manirul Islam, Charles Budde, Stuart J. Rowan

研究成果: Article

27 引用 (Scopus)

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A series of ethylene-vinyl chloride-like copolymers were prepared by ring-opening metathesis polymerization (ROMP). The route to these materials included the bulk polymerization of 5-chlorocyclooctene and 5,6-dichlorocyclooctene with the first-generation Grubbs' catalyst, followed by diimide hydrogenation of the resulting unsaturated polymers. In addition, the amount of chlorine in these materials was varied by the copolymerization of 5-chlorocyclooctene with cyclooctene. These materials were fully characterized by NMR (1H and 18C), gel permeation chromatography, and Fourier transform infrared spectroscopy. Finally, hydroboration was carried out on the ROMP product of 5-chlorocyclooctene to yield a polymer, which was effectively a vinyl alcoholvinyl chloride-ethylene terpolymer.

元の言語English
ページ(範囲)2107-2116
ページ数10
ジャーナルJournal of Polymer Science, Part A: Polymer Chemistry
41
発行部数13
DOI
出版物ステータスPublished - 2003 7 1
外部発表Yes

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ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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