Ring-opening metathesis polymerization as a route to controlled copolymers of ethylene and polar monomers: Synthesis of ethylene-vinyl chloride-like copolymers

Hongli Yang, Manirul Islam, Charles Budde, Stuart J. Rowan*

*この研究の対応する著者

研究成果: Article査読

30 被引用数 (Scopus)

抄録

A series of ethylene-vinyl chloride-like copolymers were prepared by ring-opening metathesis polymerization (ROMP). The route to these materials included the bulk polymerization of 5-chlorocyclooctene and 5,6-dichlorocyclooctene with the first-generation Grubbs' catalyst, followed by diimide hydrogenation of the resulting unsaturated polymers. In addition, the amount of chlorine in these materials was varied by the copolymerization of 5-chlorocyclooctene with cyclooctene. These materials were fully characterized by NMR (1H and 18C), gel permeation chromatography, and Fourier transform infrared spectroscopy. Finally, hydroboration was carried out on the ROMP product of 5-chlorocyclooctene to yield a polymer, which was effectively a vinyl alcoholvinyl chloride-ethylene terpolymer.

本文言語English
ページ(範囲)2107-2116
ページ数10
ジャーナルJournal of Polymer Science, Part A: Polymer Chemistry
41
13
DOI
出版ステータスPublished - 2003 7月 1
外部発表はい

ASJC Scopus subject areas

  • ポリマーおよびプラスチック
  • 材料化学

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