Robust anion conductive polymers containing perfluoroalkylene and pendant ammonium groups for high performance fuel cells

Hideaki Ono, Taro Kimura, Aoi Takano, Koichiro Asazawa, Junpei Miyake, Junji Inukai, Kenji Miyatake*

*この研究の対応する著者

研究成果: Article査読

61 被引用数 (Scopus)

抄録

A novel series of ammonium-containing copolymers (QPAF-4) were designed and synthesized as anion exchange membranes for alkaline fuel cell applications. The copolymers were prepared via a nickel promoted polycondensation reaction with high molecular weights (Mw = 72.7-276.4 kDa as precursors) and were composed of perfluoroalkylene and fluorenyl groups with pendant ammonium groups. The QPAF-4 membrane with optimized copolymer composition and ion exchange capacity exhibited high hydroxide ion conductivity (86.2 mS cm-1 in water at 80 °C) and excellent mechanical properties (large elongation at break = 269%). A severe alkaline stability test of the QPAF-4 membranes in 1 M KOH at 80 °C for 1000 h and the post-test analyses of the 1H NMR spectra, solubility, and mechanical properties revealed minor, or no, changes in the chemical structure and properties. Alkaline fuel cells using the QPAF-4 membrane were operated using hydrazine as a fuel and oxygen or air as oxidant to achieve the high maximum power density of 515 mW cm-2. The durability of the membrane was also confirmed in the operating fuel cell at a constant current density for longer than 1000 h.

本文言語English
ページ(範囲)24804-24812
ページ数9
ジャーナルJournal of Materials Chemistry A
5
47
DOI
出版ステータスPublished - 2017
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)
  • 再生可能エネルギー、持続可能性、環境
  • 材料科学(全般)

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