Role of cubic siloxane cages in mesostructure formation and photoisomerization of azobenzeneSiloxane hybrid

Sufang Guo, Jun Sasaki, Shiho Tsujiuchi, Shintaro Hara, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima

研究成果: Article査読

8 被引用数 (Scopus)

抄録

A mesostructured siloxane-based hybrid film is formed by the self-assembly of cubic, double-four-ring (D4R) siloxanes mono-functionalized with azobenzene. The azobenzene groups in the film exhibit reversible and a high degree of transcis isomerization upon UVvis irradiation. The bulky D4R cages play an important role in both the formation of cylindrical assemblies and the improvement of the photoisomerization behavior as compared with conventional azobenzenesiloxane hybrid materials.

本文言語English
ページ(範囲)1237-1239
ページ数3
ジャーナルChemistry Letters
46
8
DOI
出版ステータスPublished - 2017

ASJC Scopus subject areas

  • Chemistry(all)

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