Role of cubic siloxane cages in mesostructure formation and photoisomerization of azobenzeneSiloxane hybrid

Sufang Guo, Jun Sasaki, Shiho Tsujiuchi, Shintaro Hara, Hiroaki Wada, Kazuyuki Kuroda, Atsushi Shimojima

    研究成果: Article

    6 引用 (Scopus)

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    A mesostructured siloxane-based hybrid film is formed by the self-assembly of cubic, double-four-ring (D4R) siloxanes mono-functionalized with azobenzene. The azobenzene groups in the film exhibit reversible and a high degree of transcis isomerization upon UVvis irradiation. The bulky D4R cages play an important role in both the formation of cylindrical assemblies and the improvement of the photoisomerization behavior as compared with conventional azobenzenesiloxane hybrid materials.

    元の言語English
    ページ(範囲)1237-1239
    ページ数3
    ジャーナルChemistry Letters
    46
    発行部数8
    DOI
    出版物ステータスPublished - 2017

    ASJC Scopus subject areas

    • Chemistry(all)

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