Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids

Yooichiroh Maruyama, Takao Sezaki, Masafumi Tekawa, Toshiaki Sakamoto, Isao Shimizu, Akio Yamamoto

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Ruthenium-catalysed reductive cleavage reactions of allylic carboxylates and carbonates with formic acid and triethylamine to give olefins were explored. As an application of the ruthenium-catalysed processes, a new synthetic route to α-hydroxy acids has been discovered. The reductive cleavage of allylic esters is considered to proceed through π-allylruthenium intermediates.

本文言語English
ページ(範囲)257-264
ページ数8
ジャーナルJournal of Organometallic Chemistry
473
1-2
DOI
出版ステータスPublished - 1994 6 28

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

フィンガープリント 「Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル