抄録
Ruthenium-catalysed reductive cleavage reactions of allylic carboxylates and carbonates with formic acid and triethylamine to give olefins were explored. As an application of the ruthenium-catalysed processes, a new synthetic route to α-hydroxy acids has been discovered. The reductive cleavage of allylic esters is considered to proceed through π-allylruthenium intermediates.
本文言語 | English |
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ページ(範囲) | 257-264 |
ページ数 | 8 |
ジャーナル | Journal of Organometallic Chemistry |
巻 | 473 |
号 | 1-2 |
DOI | |
出版ステータス | Published - 1994 6 28 |
ASJC Scopus subject areas
- Biochemistry
- Chemical Engineering (miscellaneous)
- Inorganic Chemistry
- Organic Chemistry
- Physical and Theoretical Chemistry
- Materials Science (miscellaneous)
- Materials Chemistry