抄録
Ruthenium-catalysed reductive cleavage reactions of allylic carboxylates and carbonates with formic acid and triethylamine to give olefins were explored. As an application of the ruthenium-catalysed processes, a new synthetic route to α-hydroxy acids has been discovered. The reductive cleavage of allylic esters is considered to proceed through π-allylruthenium intermediates.
本文言語 | English |
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ページ(範囲) | 257-264 |
ページ数 | 8 |
ジャーナル | Journal of Organometallic Chemistry |
巻 | 473 |
号 | 1-2 |
DOI | |
出版ステータス | Published - 1994 6月 28 |
ASJC Scopus subject areas
- 生化学
- 化学工学(その他)
- 無機化学
- 有機化学
- 物理化学および理論化学
- 材料科学(その他)
- 材料化学