Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids

Yooichiroh Maruyama; Takao Sezaki; Masafumi Tekawa; Toshiaki Sakamoto; Isao Shimizu; Akio Yamamoto

doi:10.1016/0022-328X(94)80126-6

Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids

Yooichiroh Maruyama, Takao Sezaki, Masafumi Tekawa, Toshiaki Sakamoto, Isao Shimizu, Akio Yamamoto

早稲田大学

研究成果: Article › 査読

10 被引用数 (Scopus)

抄録

Ruthenium-catalysed reductive cleavage reactions of allylic carboxylates and carbonates with formic acid and triethylamine to give olefins were explored. As an application of the ruthenium-catalysed processes, a new synthetic route to α-hydroxy acids has been discovered. The reductive cleavage of allylic esters is considered to proceed through π-allylruthenium intermediates.

本文言語	English
ページ（範囲）	257-264
ページ数	8
ジャーナル	Journal of Organometallic Chemistry
巻	473
号	1-2
DOI	https://doi.org/10.1016/0022-328X(94)80126-6
出版ステータス	Published - 1994 6 28

ASJC Scopus subject areas

Biochemistry
Chemical Engineering (miscellaneous)
Inorganic Chemistry
Organic Chemistry
Physical and Theoretical Chemistry
Materials Science (miscellaneous)
Materials Chemistry

文献へのアクセス

10.1016/0022-328X(94)80126-6

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引用スタイル

Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids. / Maruyama, Yooichiroh; Sezaki, Takao; Tekawa, Masafumi; Sakamoto, Toshiaki; Shimizu, Isao; Yamamoto, Akio.

In: Journal of Organometallic Chemistry, Vol. 473, No. 1-2, 28.06.1994, p. 257-264.

研究成果: Article › 査読

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