Significance of an amorphous SiO2 phase in a pseudomorph after coesite enclosed in garnet from ultrahigh-pressure eclogite, Su–Lu Belt, eastern China

Tomoki Taguchi*, Akira Miyake, Masaki Enami, Yohei Igami

*この研究の対応する著者

研究成果: Article査読

2 被引用数 (Scopus)

抄録

Here, we report the first discovery of an amorphous SiO2 phase (APSI phase) in a pseudomorph after coesite included in garnet from an ultrahigh-pressure (UHP) eclogite from the Su–Lu metamorphic belt, eastern China. Using transmission electron microscopy, Raman spectroscopy and selected area electron diffraction, we show that the internal structure of the pseudomorph consists of an APSI phase with nano/submicrocrystalline particles of quartz and a polycrystalline K-bearing fibrous sheet-silicate phase (KFSS phase). The APSI phase-bearing aggregates included in the garnet might have formed by reactions involving a supercritical fluid during exhumation by the following processes: (1) the development of radial cracks within the host garnet by the phase transition of coesite to quartz; (2) the decomposition of a part of the pseudomorph following infiltration of supercritical fluid; (3) the precipitation of the KFSS phase from the fluid phase during subsequent exhumation and cooling, which was likely promoted by a change in the metamorphic fluid from supercritical and/or subcritical to aqueous fluid; and (4) the rapid precipitation of the APSI phase under a metastable (non-equilibrium) state, such as quenching, during a later stage of the exhumation. Whether the APSI phase generally formed during exhumation and survived widely throughout the Su-Lu terrane is unknown. However, the presence of the APSI phase in a UHP eclogite provides new insight into the geodynamic phenomena occurring at continental collision zones.

本文言語English
ページ(範囲)843-854
ページ数12
ジャーナルJournal of Metamorphic Geology
36
7
DOI
出版ステータスPublished - 2018 9月
外部発表はい

ASJC Scopus subject areas

  • 地質学
  • 地球化学および岩石学

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