Simple, Effective Molecular Strategy for the Design of Fuel Cell Membranes: Combination of Perfluoroalkyl and Sulfonated Phenylene Groups

Takashi Mochizuki, Makoto Uchida, Kenji Miyatake

研究成果: Article

16 引用 (Scopus)

抜粋

Proton-conducting membranes are key materials in polymer electrolyte fuel cells. In addition to high proton conductivity and durability, a membrane must also support good electrocatalytic performance of the catalyst layer at the membrane-electrode interface. We herein propose an effective molecular approach to the design of high-performance proton-conducting membranes designed for fuel cell applications. Our new copolymer (SPAF) is a simple combination of perfluoroalkylene and sulfonated phenylene groups. Because this ionomer membrane exhibits a well-controlled finely phase-separated morphology, based on the distinct hydrophilic-hydrophobic differences along with the polymer chain, it functions well in an operating fuel cell with good durability under practical conditions. The advantages of this ionomer, unlike typical perfluorosulfonic acid ionomers (e.g., Nafion), include easy synthesis and versatility in molecular structure, enabling the fine-tuning of membrane properties.

元の言語English
ページ(範囲)348-352
ページ数5
ジャーナルACS Energy Letters
1
発行部数2
DOI
出版物ステータスPublished - 2016 8 12
外部発表Yes

ASJC Scopus subject areas

  • Chemistry (miscellaneous)
  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Energy Engineering and Power Technology
  • Materials Chemistry

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