Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers

Satoshi Tsuneda; Kyoichi Saito; Shintaro Furusaki; Takanobu Sugo; Keizo Makuuchi

doi:10.1021/ie00019a600

Simple Introduction of Sulfonic Acid Group onto Polyethylene by Radiation-Induced Cografting of Sodium Styrenesulfonate with Hydrophilic Monomers

Satoshi Tsuneda, Kyoichi Saito^*, Shintaro Furusaki, Takanobu Sugo, Keizo Makuuchi

^*この研究の対応する著者

研究成果: Article › 査読

20 被引用数 (Scopus)

抄録

The sulfonic acid (SO₃H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO₃H density of 2.5 mol/kg of the H-type product.

本文言語	English
ページ（範囲）	1464-1470
ページ数	7
ジャーナル	Industrial and Engineering Chemistry Research
巻	32
号	7
DOI	https://doi.org/10.1021/ie00019a600
出版ステータス	Published - 1993 1月 1
外部発表	はい

ASJC Scopus subject areas

化学 (全般)
化学工学（全般）
産業および生産工学

文献へのアクセス

10.1021/ie00019a600

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引用スタイル

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abstract = "The sulfonic acid (SO3H) group was readily introduced into a polyethylene (PE) membrane by radiation-induced cografting of sodium styrenesulfonate (SSS) with hydrophilic monomers such as acrylic acid (AAc) and hydroxyethyl methacrylate (HEMA). The density of SSS grafted onto the PE membrane was determined as a function of molar ratio of hydrophilic monomer to SSS in the monomer mixture. Immersion of the electron-beam-irradiated PE membrane into the mixture of SSS and HEMA for 5 h at 323 K provided the SO3H density of 2.5 mol/kg of the H-type product.",

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AU - Makuuchi, Keizo

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