Single Atom-Based Nanoarchitectured Electrodes for High-Performance Lithium–Sulfur Batteries

Jie Wang, Bing Ding, Xiangjun Lu, Hiroki Nara, Yoshiyuki Sugahara, Yusuke Yamauchi*

*この研究の対応する著者

研究成果: Review article査読

3 被引用数 (Scopus)

抄録

Lithium−sulfur (Li−S) batteries have attracted particular interest as promising next-generation energy storage devices because of their high theoretical energy density and low cost. The real performance of Li−S batteries is, however, far from achieving the expected values, even when using a porous, highly conductive host of sulfurs to improve their electric conductivity and accommodate their volume changes. The performance restrictions are mainly attributable to the slow reaction kinetics of converting lithium polysulfides species to lithium sulfide and elemental sulfur during the charging and discharging processes, respectively. Recent studies show that single-atom catalysts (SACs) with superior catalytic activity offer an effective strategy for solving this tough issue. The recent advances in utilizing SACs for Li−S batteries, which involve catalyst preparation, battery performance, and mechanistic insights, are summarized here. Modification of the cathodes and separators with SACs helps to absorb polysulfide and promote their conversion kinetics, thus suppressing the notorious “shuttle effect.” In addition, the introduction of SACs into Li−S batteries promotes the efficiency of Li stripping/plating and prevents the growth of Li dendrites. Overall, the boost effects of SAC on Li−S batteries performance are noticeable and deserving of more research attention to develop better Li−S batteries.

本文言語English
論文番号2002159
ジャーナルAdvanced Materials Interfaces
8
8
DOI
出版ステータスPublished - 2021 4 23

ASJC Scopus subject areas

  • 材料力学
  • 機械工学

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