抄録
The skeleton <̂>side-group interaction due to <̂>-<̂ mixing in organopolysilane <>(SiXY)n <> where X and Y are methyl (Me) and phenyl (<>) groups, has been theoretically investigated. The results are discussed on the basis of uv photoemission experiments. The <>-<> interaction at the valence-band edge produces not only the delocalized <> states along the Si skeleton, but also the localized <> states in the individual <> side groups. On the other hand, the <>*-<>* interaction at the conduction-band edge is inhibited owing to the orbital symmetry. This paper also presents the results of theoretical investigations on the influence of side-group substitution and of <>side-group rotation on the electron distribution along the Si skeleton.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 8129-8137 |
| ページ数 | 9 |
| ジャーナル | Physical Review B |
| 巻 | 36 |
| 発行部数 | 15 |
| DOI | |
| 出版物ステータス | Published - 1987 |
| 外部発表 | Yes |
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ASJC Scopus subject areas
- Condensed Matter Physics
これを引用
Skeleton side-group interaction in organopolysilane. / Takeda, Kyozaburo; Fujino, Masaie; Seki, Kazuhiko; Inokuchi, Hiroo.
：: Physical Review B, 巻 36, 番号 15, 1987, p. 8129-8137.研究成果: Article
}
TY - JOUR
T1 - Skeleton side-group interaction in organopolysilane
AU - Takeda, Kyozaburo
AU - Fujino, Masaie
AU - Seki, Kazuhiko
AU - Inokuchi, Hiroo
PY - 1987
Y1 - 1987
N2 - The skeleton <̂>side-group interaction due to <̂>-<̂ mixing in organopolysilane <>(SiXY)n <> where X and Y are methyl (Me) and phenyl (<>) groups, has been theoretically investigated. The results are discussed on the basis of uv photoemission experiments. The <>-<> interaction at the valence-band edge produces not only the delocalized <> states along the Si skeleton, but also the localized <> states in the individual <> side groups. On the other hand, the <>*-<>* interaction at the conduction-band edge is inhibited owing to the orbital symmetry. This paper also presents the results of theoretical investigations on the influence of side-group substitution and of <>side-group rotation on the electron distribution along the Si skeleton.
AB - The skeleton <̂>side-group interaction due to <̂>-<̂ mixing in organopolysilane <>(SiXY)n <> where X and Y are methyl (Me) and phenyl (<>) groups, has been theoretically investigated. The results are discussed on the basis of uv photoemission experiments. The <>-<> interaction at the valence-band edge produces not only the delocalized <> states along the Si skeleton, but also the localized <> states in the individual <> side groups. On the other hand, the <>*-<>* interaction at the conduction-band edge is inhibited owing to the orbital symmetry. This paper also presents the results of theoretical investigations on the influence of side-group substitution and of <>side-group rotation on the electron distribution along the Si skeleton.
UR - http://www.scopus.com/inward/record.url?scp=0001413707&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0001413707&partnerID=8YFLogxK
U2 - 10.1103/PhysRevB.36.8129
DO - 10.1103/PhysRevB.36.8129
M3 - Article
AN - SCOPUS:0001413707
VL - 36
SP - 8129
EP - 8137
JO - Physical Review B-Condensed Matter
JF - Physical Review B-Condensed Matter
SN - 0163-1829
IS - 15
ER -