Smart coatings: Nanostructured conjugated polymer network ultrathin film using the precursor polymer approach

Rigoberto Advincula*

*この研究の対応する著者

研究成果: Article

3 被引用数 (Scopus)

抄録

Nanostructured conjugated polymer network ultrathin film using the precursor polymer approach was studied. The conjugated polymers are formed in-situ as the monomers are polymerized (radical cation mechanism) and deposited on a conductive electrode. The synthesis of the polymers was done either by polymer analogous reactions or through direct polymerization of vinyl monomers containing electropolymerizable side-groups. The precursor polymers were then crosslinked by electropolymerization and monitored by cyclic voltammetry at various solvents, substrates, solution concentrations, and counter electrolytes. Most of the films investigated showed reversible color changes (electrochromism) during the redox process and CV cycling. X-ray photoelectron spectroscopy (XPS), and FTIR spectroscopy and AFM revealed interesting deposition, doping, morphology, and crosslinking chemistry for these conjugated polymer films.

本文言語English
ページ34-37
ページ数4
5
No.2
専門出版物CoatingsTech
出版ステータスPublished - 2008
外部発表はい

ASJC Scopus subject areas

  • コロイド化学および表面化学
  • 表面および界面
  • 表面、皮膜および薄膜
  • 化学 (全般)

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