We have observed the prompt emission of GRB 100418A from its beginning captured by the MAXI SSC (0.7-7 keV) on board the International Space Station followed by the Swift XRT (0.3-10 keV) observation. The light curve can be fitted by a combination of a power-law component and an exponential component (the decay constant is 31.6 ± 1.6 s). The X-ray spectrum is well expressed by the Band function with Ep ≤ 8.3 keV. This is the brightest gamma-ray burst showing a very low value of Ep. It satisfies the Yonetoku relation (Ep-Lp). It is also consistent with the Amati relation (Ep-Eiso) within a 2.5σ level.
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