Attention has recently been paid to oxyfluorides, one of the mixed anion materials, because they possess unique properties for many kinds of application fields. Because the general synthesis processes for oxyfluorides are based on troublesome methods, novel safe and facile processes are required. In this study, MoO3 was solvothermally reacted with KF, RbF, and CsF at 200 °C to form potassium, rubidium, and cesium molybdenum oxyfluorides. The reaction of MoO3 with KF and RbF led to the formation of K3MoO3F3 and Rb3MoO3F3 with a known structure, respectively, while the reaction of MoO3 with CsF induced an unknown phase which should be Cs3MoO3F3 with the similar structure to those of K3MoO3F3 and Rb3MoO3F3. A3MoO3F3 (A = K, Rb, and Cs) has not been synthesized under liquid phase until now, and this research clarified this kind of the solvothermal reaction can lead to the formation of unique oxyfluorides at low temperature. In addition, Cs3MoO3F3 was converted into Cs3Mo2O6F3 by treatment with methanol, suggesting the instability of Cs3MoO3F3. This kind of conversion reaction from one oxyfluoride to the other oxyfluoride has not been reported, and the development of such chemical conversion may lead to the formation of new oxyfluorides.
ASJC Scopus subject areas
- 化学 (全般)