Spatially-resolved interfacial electrochemistry: Ohmic microscopy

Chen Youjiang, Alex Belianinov, Daniel Alberto Scherson*

*この研究の対応する著者

研究成果: Article査読

12 被引用数 (Scopus)

抄録

A method is herein described that allows spatially resolved capacitive currents at electrodelelectrolyte interfaces to be recorded in situ by monitoring the ohmic drop in the electrolyte, Δφsol, using two microreference electrodes. Measurements were performed in 0.1 M H 2SO4 aqueous solutions using Au and Pt either as single or dual working electrodes, that is, connected to one another, in an otherwise conventional three-electrode electrochemical cell. Plots of Δφ sol versus E, the potential of the dual AuIPt electrode with respect to the main reference electrode, recorded during voltammetric cycles, yielded curves bearing features characteristic of the Au|0.1 M H2SO 4 or Pt|0.1 M H2SO4 interface depending on whether the microreference electrodes were placed close to the Au or Pt electrode surface, respectively. Extensions of this methodology to measurements in the micrometer domain are discussed briefly.

本文言語English
ページ(範囲)8754-8758
ページ数5
ジャーナルJournal of Physical Chemistry C
112
24
DOI
出版ステータスPublished - 2008 6 19
外部発表はい

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 電子材料、光学材料、および磁性材料
  • 表面、皮膜および薄膜
  • エネルギー(全般)

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