Stereoselective synthesis of allylsilanes bearing tetrasubstituted olefin via 2,2-Diborylethylsilane

Kohei Endo, Akira Sakamoto, Takahiro Ohkubo, Takanori Shibata

研究成果: Article

27 引用 (Scopus)

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The regio-and stereoselective synthesis of allylsilane derivatives bearing a tetrasubstituted olefin was achieved using 2,2-diborylethylsilane as a key intermediate. The regioselective deprotonation of a 2,2-diborylethylsilane with LTMP and the subsequent nucleophilic addition to ketones gave corresponding allylsilanes in good to excellent yield with excellent stereoselectivity.

元の言語English
ページ(範囲)1440-1442
ページ数3
ジャーナルChemistry Letters
40
発行部数12
DOI
出版物ステータスPublished - 2011 12 1

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ASJC Scopus subject areas

  • Chemistry(all)

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