抜粋
The highly stereoselective total synthesis of nemorosone via a new approach to the bicyclo[3.3.1]nonane-2,4,9-trione core which features intramolecular cyclopropanation of an α-diazo ketone, stereoselective alkylation at the C8 position, and regioselective ring-opening of cyclopropane is described. The total synthesis of nemorosone includes chemo- and stereoselective hydrogenation directed by the internal alkene.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 5098-5107 |
| ページ数 | 10 |
| ジャーナル | Journal of Organic Chemistry |
| 巻 | 77 |
| 発行部数 | 11 |
| DOI | |
| 出版物ステータス | Published - 2012 6 1 |
ASJC Scopus subject areas
- Organic Chemistry
フィンガープリント Stereoselective total synthesis of nemorosone' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Uwamori, M., Saito, A., & Nakada, M. (2012). Stereoselective total synthesis of nemorosone. Journal of Organic Chemistry, 77(11), 5098-5107. https://doi.org/10.1021/jo300646j