Stereoselective total synthesis of nemorosone

Masahiro Uwamori, Aya Saito, Masahisa Nakada

研究成果: Article査読

45 被引用数 (Scopus)

抄録

The highly stereoselective total synthesis of nemorosone via a new approach to the bicyclo[3.3.1]nonane-2,4,9-trione core which features intramolecular cyclopropanation of an α-diazo ketone, stereoselective alkylation at the C8 position, and regioselective ring-opening of cyclopropane is described. The total synthesis of nemorosone includes chemo- and stereoselective hydrogenation directed by the internal alkene.

本文言語English
ページ(範囲)5098-5107
ページ数10
ジャーナルJournal of Organic Chemistry
77
11
DOI
出版ステータスPublished - 2012 6 1

ASJC Scopus subject areas

  • Organic Chemistry

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