Stereospecific transformation of a chiral pyrimidyl alkanol into L-valine

Kenso Soai, Shigehisa Tanji, Yasutaka Kodaka, Takanori Shibata

研究成果: Article査読

5 被引用数 (Scopus)

抄録

A chiral pyrimidyl alkanol with high enantiomeric excess is transformed into L-valine with high e.e. by a notable oxidative cleavage of pyrimidine ring using ruthenium oxide as a key step. This process would correlate natural α-amino acids with a chiral pyrimidyl alkanol, which is reported to possess an asymmetric autocatalytic activity with amplification of e.e.

本文言語English
ページ(範囲)241-243
ページ数3
ジャーナルEnantiomer
3
3
出版ステータスPublished - 1998 11 24
外部発表はい

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry
  • Biochemistry, Genetics and Molecular Biology(all)
  • Organic Chemistry

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