Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta; Kenichi Oyaizu; Hiroyuki Nishide

doi:10.1246/cl.2007.866

Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta, Kenichi Oyaizu, Hiroyuki Nishide^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

78 被引用数 (Scopus)

抄録

Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp ² character of nitrogens which is intermediate between the purely sp ² and sp ³ nitrogens in oxoammonium cations and amines, respectively.

本文言語	English
ページ（範囲）	866-867
ページ数	2
ジャーナル	Chemistry Letters
巻	36
号	7
DOI	https://doi.org/10.1246/cl.2007.866
出版ステータス	Published - 2007 7月 5

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.2007.866

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title = "Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals",

abstract = "Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.",

author = "Yasunori Yonekuta and Kenichi Oyaizu and Hiroyuki Nishide",

year = "2007",

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AU - Yonekuta, Yasunori

AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

PY - 2007/7/5

Y1 - 2007/7/5

N2 - Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.

AB - Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.

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JO - Chemistry Letters

JF - Chemistry Letters

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Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

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