Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta; Kenichi Oyaizu; Hiroyuki Nishide

doi:10.1246/cl.2007.866

Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

Yasunori Yonekuta, Kenichi Oyaizu, Hiroyuki Nishide^*

^*この研究の対応する著者

先進理工学部

研究成果 › 査読

72 被引用数 (Scopus)

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Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp ² character of nitrogens which is intermediate between the purely sp ² and sp ³ nitrogens in oxoammonium cations and amines, respectively.

本文言語	English
ページ（範囲）	866-867
ページ数	2
ジャーナル	Chemistry Letters
巻	36
号	7
DOI	https://doi.org/10.1246/cl.2007.866
出版ステータス	Published - 2007 7 5

ASJC Scopus subject areas

化学 (全般)

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10.1246/cl.2007.866

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title = "Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals",

abstract = "Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.",

author = "Yasunori Yonekuta and Kenichi Oyaizu and Hiroyuki Nishide",

year = "2007",

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AU - Yonekuta, Yasunori

AU - Oyaizu, Kenichi

AU - Nishide, Hiroyuki

PY - 2007/7/5

Y1 - 2007/7/5

N2 - Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.

AB - Structures and electrochemical behaviors of nitroxide radicals reveal that their rapid and reversible redox reactions are based not only on their chemical stability but also on the increased sp 2 character of nitrogens which is intermediate between the purely sp 2 and sp 3 nitrogens in oxoammonium cations and amines, respectively.

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DO - 10.1246/cl.2007.866

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JO - Chemistry Letters

JF - Chemistry Letters

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Structural implication of oxoammonium cations for reversible organic one-electron redox reaction to nitroxide radicals

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