Structure and Photoelectrochemical Properties of Laminated Monoparticle Layers of CdS and ZnS on Gold

Takuya Nakanishi, Bunsho Ohtani, Kohei Uosaki*


研究成果: Conference article査読

22 被引用数 (Scopus)


Monolayers of CdS and ZnS nanoparticles and their layer-by-layer composite films were fabricated on a gold substrate that was precoated with a self-assembled monolayer (SAM) of 1,6-hexanedithiol. Semiconductor nanoparticles (∼4 nm in diameter) were prepared in reversed micelles. Evidence for the attachment of nanoparticles on SAM was obtained by X-ray photoelectron spectroscopy. A photoinduced anodic current was observed when the semiconductor nanoparticle electrodes were immersed in an electrolyte solution containing triethanolamine as the electron donor. The photocurrent action spectra of nanoparticle monolayers were in good agreement with the absorption spectra of nanoparticle dispersions before immobilization, indicating that the nanoparticles were immobilized on the substrate without changing their particle size. Layer-by-layer composite films of CdS and ZnS showed photoresponse depending on the order of accumulation. This indicates the successful fabrication of a layer-by-layer structure that affects the electron transfer through nanoparticles and the penetration of the electrolyte solution.

ジャーナルJapanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
1 B
出版ステータスPublished - 1999
イベントProceedings of the 1998 International Symposium on Formation, Physics and Device Application of Quantum Dot Structures, QDS-98 - Sapporo, Japan
継続期間: 1998 5月 311998 6月 4

ASJC Scopus subject areas

  • 工学(全般)
  • 物理学および天文学(全般)


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