Structure and stability of water soluble (NH4)8[Ti4(C6H4O 7)4(O2)4]·8H2O

M. Kakihana, M. Tada, M. Shiro, V. Petrykin, M. Osada, Y. Nakamura

研究成果: Article査読

139 被引用数 (Scopus)

抄録

Ammonium citratoperoxotitanate(IV), (NH4)8[Ti4(C6H4O 7)4(O2)4]·8H2O, was isolated in the solid form. Its crystal structure was solved and refined using single-crystal X-ray data. The compound crystallizes in a monoclinic cell With a = 10.237(2).Å, b = 17.537(4) Å, c = 14.713(3) Å, β = 100.35(1)° (Z = 2, fw = 1360.40, ρcalc = 1.74 g/cm3) and space group P21/n (No. 14). The determined structure of the titanium complex agrees well with the Raman and NMR spectroscopic data. We speculate that tight coordination of titanium in the complex molecule is responsible for the high stability of this compound against hydrolysis.

本文言語English
ページ(範囲)891-894
ページ数4
ジャーナルInorganic Chemistry
40
5
DOI
出版ステータスPublished - 2001 2 26
外部発表はい

ASJC Scopus subject areas

  • 無機化学

フィンガープリント

「Structure and stability of water soluble (NH<sub>4</sub>)<sub>8</sub>[Ti<sub>4</sub>(C<sub>6</sub>H<sub>4</sub>O <sub>7</sub>)<sub>4</sub>(O<sub>2</sub>)<sub>4</sub>]·8H<sub>2</sub>O」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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