Sulfated zirconia nanoparticles as a proton conductor for fuel cell electrodes

Satoshi Tominaka, Naohisa Akiyama, Fausto Croce, Toshiyuki Momma, Bruno Scrosati, Tetsuya Osaka*


研究成果: Article査読

26 被引用数 (Scopus)


Sulfated zirconia nanoparticles are evaluated as a possible alternative for a solid proton conductor in a fuel-cell catalyst layer. Two methods are applied for the synthesis of the nanoparticles, i.e.: (i) a conventional method treating ZrO2 particles in sulfuric acid, and (ii) a solvent-free method directly synthesizing sulfated zirconia nanoparticles through the thermal decomposition of a mixture of ZrOCl2 and (NH4)2SO4. The nanoparticles synthesized by the solvent-free method have a size of 5-10 nm and an amorphous structure, and moreover their properties are promising in view of the application. In particular, the proton conductivity of the nanoparticles is high enough, i.e. of the 10-2 S cm-1 order, to be comparable to that of Nafion. Even though they possibly reduce the activity of Pt catalyst, layers containing sulfated zirconia as a proton conductor prove to be active as catalyst in fuel cell prototypes. Compared with conventional, Nafion-based cells, the maximum power density of the cells using sulfated zirconia is about one third. We believe that improvement in the preparation procedures for catalyst layers and membrane electrode assemblies will improve the cell performance. Therefore sulfated zirconia can be a valid proton conductor for fuel cell application.

ジャーナルJournal of Power Sources
出版ステータスPublished - 2008 12月 1

ASJC Scopus subject areas

  • 再生可能エネルギー、持続可能性、環境
  • エネルギー工学および電力技術
  • 物理化学および理論化学
  • 電子工学および電気工学


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