Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

Takanori Shibata; Akihito Mitake; Yosuke Akiyama; Kyalo Stephen Kanyiva

doi:10.1039/c7cc04997h

Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

Takanori Shibata^*, Akihito Mitake, Yosuke Akiyama, Kyalo Stephen Kanyiva

^*この研究の対応する著者

研究成果 › 査読

21 被引用数 (Scopus)

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Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

本文言語	English
ページ（範囲）	9016-9019
ページ数	4
ジャーナル	Chemical Communications
巻	53
号	64
DOI	https://doi.org/10.1039/c7cc04997h
出版ステータス	Published - 2017

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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abstract = "Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.",

author = "Takanori Shibata and Akihito Mitake and Yosuke Akiyama and Kanyiva, {Kyalo Stephen}",

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AU - Shibata, Takanori

AU - Mitake, Akihito

AU - Akiyama, Yosuke

AU - Kanyiva, Kyalo Stephen

PY - 2017

Y1 - 2017

N2 - Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

AB - Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

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U2 - 10.1039/c7cc04997h

DO - 10.1039/c7cc04997h

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Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

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