Sulfur-directed carbon-sulfur bond cleavage for Rh-catalyzed regioselective alkynylthiolation of alkynes

Takanori Shibata, Akihito Mitake, Yosuke Akiyama, Kyalo Stephen Kanyiva

研究成果: Article査読

12 被引用数 (Scopus)

抄録

Sulfur-directed sp C-S bond cleavage along with a regioselective reaction with alkynes proceeded to give (Z)-enyne sulfides in high to excellent yields. Mechanistic studies were conducted, including characterization of an intermediate. An intramolecular variant realized the construction of a dibenzodithiepin skeleton, which is a seven-membered ring with two sulfur atoms.

本文言語English
ページ(範囲)9016-9019
ページ数4
ジャーナルChemical Communications
53
64
DOI
出版ステータスPublished - 2017 1 1

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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