Synthesis and Characterization of 4-Vinylimidazolium/Styrene-Cografted Anion-Conducting Electrolyte Membranes

Takashi Hamada*, Kimio Yoshimura, Kota Takeuchi, Shun Watanabe, Yue Zhao, Akihiro Hiroki, Tokio Hagiwara, Hideyuki Shishitani, Susumu Yamaguchi, Hirohisa Tanaka, Aurel Radulescu, Kenji Ohwada, Yasunari Maekawa

*この研究の対応する著者

研究成果: Article査読

1 被引用数 (Scopus)

抄録

The β-hydrogen-free imidazole monomer, 2-methyl-N-methyl-4(5)-vinylimidazole (2M4VIm), is synthesized to prepare anion exchange membranes (AEMs). The radiation-induced graft polymerization of 2M4VIm and styrene is performed in poly(ethylene-co-tetrafluoroethylene), followed by N-alkylation and ion exchange reactions to prepare 4-vinylimidazolium-containing AEM (2M4VIm/St-AEM). AEMs that have a 6/4 2M4VIm/St molar ratio and 1.7 mmol g−1 ion exchange capacity (IEC) result in 75 mS cm−1 conductivity and 60% water uptake at room temperature in water, demonstrating enhanced values compared to previously reported 2-methyl-N-vinylimidazolium-containing AEMs (2MNVIm/St-AEM) that have a similar comonomer ratio and IEC. The small-angle neutron scattering measurements of dry and swollen 2M4VIm/St-AEM reveal hydrophilic/hydrophobic two-phase separation, as observed for 2MNVIm/St-AEM with a similar Im/St composition. 2M4VIm/St-AEMs exhibit higher alkaline stability in 1 m KOH at 80 °C at an early stage owing to the suppression of imidazolium β-elimination but lower long-term stability than that of 2MNVIm/St-AEM due to the ring-opening reaction of the imidazolium group due to its outward orientation from the graft main chain.

本文言語English
論文番号2100028
ジャーナルMacromolecular Chemistry and Physics
222
11
DOI
出版ステータスPublished - 2021 6月
外部発表はい

ASJC Scopus subject areas

  • 凝縮系物理学
  • 物理化学および理論化学
  • ポリマーおよびプラスチック
  • 有機化学
  • 材料化学

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