Synthesis and characterization of a new C2-symmetrical chiral tridentate N-heterocyclic carbene ligand coordinated Cr(III) complex

Yuta Uetake, Takashi Niwa, Masahisa Nakada*

*この研究の対応する著者

研究成果: Article査読

5 被引用数 (Scopus)

抄録

The preparation of a new C2-symmetrical chiral tridentate N-heterocyclic carbene (NHC) ligand coordinated Cr(III) complex is described. The new NHC ligand was prepared as its AgBr complex, which was stable but smoothly underwent carbene exchange reaction with CrCl2 to afford the new NHC ligand coordinated Cr(III) complex. The X-ray crystallographic analysis of the Cr(III) complex revealed its distorted octahedral form. The Cr(III) complex mediated reaction of allylbromide with benzaldehyde did not afford products under the catalytic conditions reported by us.

本文言語English
ページ(範囲)158-162
ページ数5
ジャーナルTetrahedron Asymmetry
26
2-3
DOI
出版ステータスPublished - 2015 2 15

ASJC Scopus subject areas

  • 触媒
  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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