Synthesis and characterization of microporous layered zirconium phenylphosphonate

N. K. Mal*, M. Sasidharan, M. Fujiwara, Y. Yamada, M. Matsukata

*この研究の対応する著者

研究成果査読

2 被引用数 (Scopus)

抄録

Microporous layered zirconium phenylphosphonate, Zr(O3P-C 6H5)2 was prepared in presence of sodium dodecylsulfate (SDS), for the first time. Interplanar spacing (d001) and surface area of microporous zirconium phenylphosphonate are 1.47 nm and 198 m2g-1, respectively. FT-IR spectrum indicates absence or negligible amount of hydroxyls groups in zirconium phenylphosphonate sample, 31P solid MAS NMR also confirms the presence of trace amount of hydroxyl groups in zirconium phenylphosphonate. The presence of tetra-coordinated phosphorous ions and hexa-coordinated zirconium ions were realized by the 31P solid MAS NMR and UV-visible, respectively. Sulfonated derivative of zirconium phenylphosphonate, Zr(O3PC 6H4SO3H)19 (O3PC 6H5)0.1·3.7H2O were also prepared.

本文言語English
ページ(範囲)1153-1159
ページ数7
ジャーナルStudies in Surface Science and Catalysis
154 A
出版ステータスPublished - 2004 1 1

ASJC Scopus subject areas

  • 触媒
  • 凝縮系物理学
  • 物理化学および理論化学
  • 表面、皮膜および薄膜
  • 材料化学

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