Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Keiko Nunokawa, Satoru Onaka*, Tadashi Yamaguchi, Tasuku Ito, Seiji Watase, Masami Nakamoto

*この研究の対応する著者

研究成果: Article査読

22 被引用数 (Scopus)

抄録

A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.

本文言語English
ページ(範囲)1601-1602
ページ数2
ジャーナルBulletin of the Chemical Society of Japan
76
8
DOI
出版ステータスPublished - 2003 8月
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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