Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Keiko Nunokawa; Satoru Onaka; Tadashi Yamaguchi; Tasuku Ito; Seiji Watase; Masami Nakamoto

doi:10.1246/bcsj.76.1601

Synthesis and characterization of the Au₁₁ cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

Keiko Nunokawa, Satoru Onaka^*, Tadashi Yamaguchi, Tasuku Ito, Seiji Watase, Masami Nakamoto

^*この研究の対応する著者

研究成果: Article › 査読

22 被引用数 (Scopus)

抄録

A new Au₁₁ cluster with (m-CF₃C₆H ₄)₃P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au₁₁X₃(PR ₃)₇ clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF₃ substituents at a meta-position of each phenyl ring of PR₃ ligands.

本文言語	English
ページ（範囲）	1601-1602
ページ数	2
ジャーナル	Bulletin of the Chemical Society of Japan
巻	76
号	8
DOI	https://doi.org/10.1246/bcsj.76.1601
出版ステータス	Published - 2003 8月
外部発表	はい

ASJC Scopus subject areas

化学 (全般)

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10.1246/bcsj.76.1601

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引用スタイル

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abstract = "A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.",

author = "Keiko Nunokawa and Satoru Onaka and Tadashi Yamaguchi and Tasuku Ito and Seiji Watase and Masami Nakamoto",

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T1 - Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

AU - Nunokawa, Keiko

AU - Onaka, Satoru

AU - Yamaguchi, Tadashi

AU - Ito, Tasuku

AU - Watase, Seiji

AU - Nakamoto, Masami

PY - 2003/8

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AB - A new Au11 cluster with (m-CF3C6H 4)3P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR 3)7 clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.

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