Synthesis and characterization of two isomers of 14π-electron germaaromatics: Kinetically stabilized 9-germaanthracene and 9-germaphenanthrene

Takahiro Sasamori; Koji Inamura; Wataru Hoshino; Norio Nakata; Yoshiyuki Mizuhata; Yasuaki Watanabe; Yukio Furukawa; Norihiro Tokitoh

doi:10.1021/om060371+

Synthesis and characterization of two isomers of 14π-electron germaaromatics: Kinetically stabilized 9-germaanthracene and 9-germaphenanthrene

Takahiro Sasamori, Koji Inamura, Wataru Hoshino, Norio Nakata, Yoshiyuki Mizuhata, Yasuaki Watanabe, Yukio Furukawa, Norihiro Tokitoh^*

^*この研究の対応する著者

先進理工学部

研究成果 › 査読

34 被引用数 (Scopus)

抄録

The first stable 9-germaanthracene and 9-germaphenanthrene were successfully synthesized by taking advantage of kinetic stabilization utilizing effective steric protection groups, Tbt and Bbt groups (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Bbt = 2,6-bis[bis(trimethylsilyl)methylJ4-[tris(trimethylsilyl)methyl]phenyl). The similarities and differences of the structures and properties between the two isomers of germaaromatics are discussed.

本文言語	English
ページ（範囲）	3533-3536
ページ数	4
ジャーナル	Organometallics
巻	25
号	15
DOI	https://doi.org/10.1021/om060371+
出版ステータス	Published - 2006 7 17

ASJC Scopus subject areas

物理化学および理論化学
有機化学
無機化学

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10.1021/om060371+

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引用スタイル

Synthesis and characterization of two isomers of 14π-electron germaaromatics : Kinetically stabilized 9-germaanthracene and 9-germaphenanthrene. / Sasamori, Takahiro; Inamura, Koji; Hoshino, Wataru; Nakata, Norio; Mizuhata, Yoshiyuki; Watanabe, Yasuaki; Furukawa, Yukio; Tokitoh, Norihiro.

In: Organometallics, Vol. 25, No. 15, 17.07.2006, p. 3533-3536.

研究成果 › 査読

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abstract = "The first stable 9-germaanthracene and 9-germaphenanthrene were successfully synthesized by taking advantage of kinetic stabilization utilizing effective steric protection groups, Tbt and Bbt groups (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Bbt = 2,6-bis[bis(trimethylsilyl)methylJ4-[tris(trimethylsilyl)methyl]phenyl). The similarities and differences of the structures and properties between the two isomers of germaaromatics are discussed.",

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AU - Inamura, Koji

AU - Hoshino, Wataru

AU - Nakata, Norio

AU - Mizuhata, Yoshiyuki

AU - Watanabe, Yasuaki

AU - Furukawa, Yukio

AU - Tokitoh, Norihiro

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