Synthesis and characterization of two isomers of 14π-electron germaaromatics: Kinetically stabilized 9-germaanthracene and 9-germaphenanthrene

Takahiro Sasamori, Koji Inamura, Wataru Hoshino, Norio Nakata, Yoshiyuki Mizuhata, Yasuaki Watanabe, Yukio Furukawa, Norihiro Tokitoh*

*この研究の対応する著者

研究成果査読

34 被引用数 (Scopus)

抄録

The first stable 9-germaanthracene and 9-germaphenanthrene were successfully synthesized by taking advantage of kinetic stabilization utilizing effective steric protection groups, Tbt and Bbt groups (Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Bbt = 2,6-bis[bis(trimethylsilyl)methylJ4-[tris(trimethylsilyl)methyl]phenyl). The similarities and differences of the structures and properties between the two isomers of germaaromatics are discussed.

本文言語English
ページ(範囲)3533-3536
ページ数4
ジャーナルOrganometallics
25
15
DOI
出版ステータスPublished - 2006 7 17

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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