Synthesis and color tuning of titanium oxide inorganic pigment by phase control and mixed-anion co-doping

Jindi Cao, Takuya Hasegawa, Yusuke Asakura, Peng Sun, Shuo Yang, Bin Li, Wenbin Cao, Shu Yin*

*この研究の対応する著者

研究成果: Article査読

2 被引用数 (Scopus)

抄録

B and N co-doped anatase, rutile, and brookite TiO2 (abbreviated as BN-Ana, BN-Rut, and BN-Bro) were successfully synthesized. The apparent color of as-obtain BN-Ana, BN-Rut and BN-Bro was red, cyan and yellow-green, respectively. The mechanisms of various coloring were concluded as the different band gap configurations and the formation of covalent B-N bonding. The nitridation time expressed less effect on changing the color. On the contrary, nitridation temperature enabled the distinct color changes by altering the brightness. Lower temperature, fewer doping concentration, and brighter apparent color, vice versa. Through tuning the brightness, a gradient of yellow-orange-red was achieved in the case of BN-Ana, as well the transitions of grey-to-cyan and white-to-pale-yellow were achieved in BN-Rut and BN-Bro, respectively. This research proposed a method for the synthesis of color-full titania pigment without the addition of other toxic transition metal elements.

本文言語English
論文番号103576
ジャーナルAdvanced Powder Technology
33
5
DOI
出版ステータスPublished - 2022 5月

ASJC Scopus subject areas

  • 化学工学(全般)
  • 材料力学

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