Synthesis and electrochemistry of schiff base cobalt(III) complexes and their catalytic activity for copolymerization of epoxide andcarbon dioxide

Xiuli Zhuang, Kenichi Oyaizu, Yongsheng Niu, Kenichiroh Koshika, Xuesi Chen*, Hiroyuki Nishide

*この研究の対応する著者

研究成果査読

17 被引用数 (Scopus)

抄録

A series of cobalt complexes with N,N,O,O-tetradentate Schiff base ligands were employed as catalysts for the alternating copolymerization of carbon dioxide and racemic propylene oxide. End group analysis of the resulting polymer provided strong evidence for a manomer insertion mechanism for the progation step, which indicated that the six-coordination arragement around the cobalt center was maintained during the catalytic cycle.

本文言語English
ページ(範囲)669-676
ページ数8
ジャーナルMacromolecular Chemistry and Physics
211
6
DOI
出版ステータスPublished - 2010 3 15

ASJC Scopus subject areas

  • 凝縮系物理学
  • 物理化学および理論化学
  • 有機化学
  • ポリマーおよびプラスチック
  • 材料化学

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