Synthesis and electrochemistry of schiff base cobalt(III) complexes and their catalytic activity for copolymerization of epoxide andcarbon dioxide

Xiuli Zhuang, Kenichi Oyaizu, Yongsheng Niu, Kenichiroh Koshika, Xuesi Chen, Hiroyuki Nishide

研究成果: Article査読

16 被引用数 (Scopus)

抄録

A series of cobalt complexes with N,N,O,O-tetradentate Schiff base ligands were employed as catalysts for the alternating copolymerization of carbon dioxide and racemic propylene oxide. End group analysis of the resulting polymer provided strong evidence for a manomer insertion mechanism for the progation step, which indicated that the six-coordination arragement around the cobalt center was maintained during the catalytic cycle.

本文言語English
ページ(範囲)669-676
ページ数8
ジャーナルMacromolecular Chemistry and Physics
211
6
DOI
出版ステータスPublished - 2010 3 15

ASJC Scopus subject areas

  • 凝縮系物理学
  • 物理化学および理論化学
  • 有機化学
  • ポリマーおよびプラスチック
  • 材料化学

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