Synthesis and functionalization of bromomethylated poly(phenylene sulfide)

Kenji Miyatake, Hiroyuki Hara, Eishun Tsuchida*

*この研究の対応する著者

研究成果: Article査読

4 被引用数 (Scopus)

抄録

A soluble poly(phenylene sulfide) (PPS) derivative was synthesized by oxidative polymerization of bis(3,5-dimethylphenyl) disulfide. The obtained poly(thio-2,6-dimethyl-1,4-phenylene) (I) (M̄w = 22900, M̄n = 8400) was brominated by the reaction with N-bromosuccinimide (NBS). The bromomethyl substituents on PPS are reactive and were converted quantitatively to hydroxymethyl groups by hydrolysis in NMP at 100°C. The reaction of the bromomethylated PPS with tertiary amines gave the quaternized polymer, which is stable up to 145°C in the solid state and in refluxing methanol.

本文言語English
ページ(範囲)1930-1934
ページ数5
ジャーナルMacromolecular Chemistry and Physics
200
8
DOI
出版ステータスPublished - 1999 8

ASJC Scopus subject areas

  • 凝縮系物理学
  • 物理化学および理論化学
  • 有機化学
  • ポリマーおよびプラスチック
  • 材料化学

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