Synthesis and magnetic properties of linear two-coordinate monomeric diaryliron(II) complexes bearing fused-ring bulky "Rind" groups

Shun Goda, Masanori Nikai, Mikinao Ito, Daisuke Hashizume, Kohei Tamao, Atsushi Okazawa*, Norimichi Kojima, Hiroyuki Fueno, Kazuyoshi Tanaka, Yoshio Kobayashi, Tsukasa Matsuo

*この研究の対応する著者

研究成果: Article査読

7 被引用数 (Scopus)

抄録

Monomeric diaryliron(II) complexes, Fe(Rind)2, have been obtained by introducing fused-ring bulky "Rind" groups. For Fe(Eind)2, a significant orbital contribution of the Fe(II) ion due to the linear two-coordination has been determined by the highly effective magnetic moment (μeff = 5.82 μB) and the extraordinarily large internal hyperfine field (Hn = ca. 140 T) in the Mössbauer spectrum. Variable-frequency out-of-phase ac susceptibility data demonstrate an effective spin-reversal barrier of Ueff = 51.2(7) cm-1 associated with the single-ion magnet behavior.

本文言語English
ページ(範囲)634-636
ページ数3
ジャーナルChemistry Letters
45
6
DOI
出版ステータスPublished - 2016
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

フィンガープリント

「Synthesis and magnetic properties of linear two-coordinate monomeric diaryliron(II) complexes bearing fused-ring bulky "Rind" groups」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル