Synthesis and magnetic property of poly[bis(4-methoxyphenyl) aminiumacetylene]s

Hidenori Murata, Daisuke Miyajima, Ryosuke Takada, Hiroyuki Nishide*

*この研究の対応する著者

研究成果査読

20 被引用数 (Scopus)

抄録

Poly[bis(4-methoxyphenyl)arniniumacetylene]s 1+ were designed and synthesized as π-conjugated polymer bearing multiple aminium radicals. Bis(4-methoxyphenyl)aminoacetylene and 1-methyl-2-bis(4-methoxyphenyl) aminoacetylene were synthesized and polymerized with a metathesis catalyst to yield poly[bis(4-methoxyphenyl)aminoacetylene] la and poly[1-methyl-2-bis(4- methoxyphenyl)aminoacetylene] 1b, respectively. The oxidation of 1 with SbCl5 gave the corresponding aminium polyradicals 1+. The introduction of a methyl group onto the polyacetylene backbone in 1b+ significantly enhanced the chemical stability or life-time of the poly(aminium radical). The high-spin ground state with an average 5 (spin quantum number) = 4/2 for lb+ was proven by magnetic susceptibility, magnetization, and ESR measurements.

本文言語English
ページ(範囲)818-825
ページ数8
ジャーナルPolymer Journal
37
11
DOI
出版ステータスPublished - 2005

ASJC Scopus subject areas

  • ポリマーおよびプラスチック
  • 材料化学

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