Synthesis and properties of norcaradiene-cycloheptatriene system fused with isoxazole ring

Nobuhiro Kanomata; Makoto Nitta; Kensuke Takahashi; Yutaka Takakura; Katsuhiro Saito

Synthesis and properties of norcaradiene-cycloheptatriene system fused with isoxazole ring

Nobuhiro Kanomata, Makoto Nitta, Kensuke Takahashi, Yutaka Takakura, Katsuhiro Saito

先進理工学部

研究成果: Article › 査読

1 被引用数 (Scopus)

抄録

Novel norcaradiene-cycloheptatriene systems fused with arylisoxazoles were synthesized and their temperature dependent ¹H nmr spectra were studied. While the fusion of isoxazole ring much shifted the norcaradiene-cycloheptatriene equilibrium to the side of norcaradiene form, the rapid isomerizations of the norcaradienes with their enantiomers were observed and their ΔG_C^{{double barred pipe}} values were obtained.

本文言語	English
ページ（範囲）	3105-3109
ページ数	5
ジャーナル	Heterocycles
巻	26
号	12
出版ステータス	Published - 1987 12 1

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

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引用スタイル

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abstract = "Novel norcaradiene-cycloheptatriene systems fused with arylisoxazoles were synthesized and their temperature dependent 1H nmr spectra were studied. While the fusion of isoxazole ring much shifted the norcaradiene-cycloheptatriene equilibrium to the side of norcaradiene form, the rapid isomerizations of the norcaradienes with their enantiomers were observed and their ΔGC{double barred pipe} values were obtained.",

author = "Nobuhiro Kanomata and Makoto Nitta and Kensuke Takahashi and Yutaka Takakura and Katsuhiro Saito",

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T1 - Synthesis and properties of norcaradiene-cycloheptatriene system fused with isoxazole ring

AU - Kanomata, Nobuhiro

AU - Nitta, Makoto

AU - Takahashi, Kensuke

AU - Takakura, Yutaka

AU - Saito, Katsuhiro

PY - 1987/12/1

Y1 - 1987/12/1

N2 - Novel norcaradiene-cycloheptatriene systems fused with arylisoxazoles were synthesized and their temperature dependent 1H nmr spectra were studied. While the fusion of isoxazole ring much shifted the norcaradiene-cycloheptatriene equilibrium to the side of norcaradiene form, the rapid isomerizations of the norcaradienes with their enantiomers were observed and their ΔGC{double barred pipe} values were obtained.

AB - Novel norcaradiene-cycloheptatriene systems fused with arylisoxazoles were synthesized and their temperature dependent 1H nmr spectra were studied. While the fusion of isoxazole ring much shifted the norcaradiene-cycloheptatriene equilibrium to the side of norcaradiene form, the rapid isomerizations of the norcaradienes with their enantiomers were observed and their ΔGC{double barred pipe} values were obtained.

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