Synthesis and Properties of Pyridine-Fused Triazolylidene-Palladium: Catalyst for Cross-Coupling Using Chloroarenes and Nitroarenes

Keiichiro Iizumi, Keito P. Nakayama, Kenta Kato, Kei Muto, Junichiro Yamaguchi*

*この研究の対応する著者

研究成果: Article査読

2 被引用数 (Scopus)

抄録

The synthesis and catalytic activity of pyridine-fused triazolylidene as a novel abnormal N-heterocyclic carbene (aNHC) ligand is described. The evaluation of physical properties using X-ray crystallographic analysis and infrared spectroscopy revealed that these triazolylidenes have a high electron-donating ability toward the metal center. The application of this triazolylidene to the palladium-catalyzed cross-coupling of chloroarenes and nitroarenes with arylboronic acids showcased its ability to activate C-Cl and C-NO2 bonds.

本文言語English
ページ(範囲)11909-11918
ページ数10
ジャーナルJournal of Organic Chemistry
87
17
DOI
出版ステータスPublished - 2022 9月 2

ASJC Scopus subject areas

  • 有機化学

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