Synthesis and properties of stable 2-metallanaphthalenes of heavier group 14 elements

Yoshiyuki Mizuhata, Takahiro Sasamori, Noriyoshi Nagahora, Yasuaki Watanabe, Yukio Furukawa, Norihiro Tokitoh*

*この研究の対応する著者

研究成果査読

24 被引用数 (Scopus)

抄録

The first stable neutral stannaaromatic compound, 2-stannanaphthalene 1a, was synthesized by taking advantage of an extremely bulky and efficient steric protection group, 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt). The molecular structure and aromaticity of 1a were discussed on the basis of X-ray crystallographic analysis, NMR, UV-vis, and Raman spectroscopy, cyclic voltammetry, and theoretical calculations. 2-Germanaphthalene 2a, which has a framework similar to that of 1a, was synthesized for comparison, and systematic elucidation was made for the properties of 2-metallanaphthalene systems containing a heavier group 14 element (Si, Ge, or Sn).

本文言語English
ページ(範囲)4409-4418
ページ数10
ジャーナルDalton Transactions
33
DOI
出版ステータスPublished - 2008 8 20

ASJC Scopus subject areas

  • 無機化学

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