@article{2bf49db5be144d6dbf9510087c229ea2,
title = "Synthesis and Reaction of ortho-Benzoquinone Monohemiaminals",
abstract = "The preparation and reactions of ortho-benzoquinone monohemiaminals are described. The oxidative dearomatization of phenols bearing amino alcohol groups induced N-cyclization to afford ortho-benzoquinone monohemiaminals. The N-cyclization stereoselectively affords the product when a chiral amino alcohol is used as the substituent. The chiral ortho-benzoquinone monohemiaminal undergoes stereoselective Diels-Alder reactions with electron-deficient alkenes, as expected, confirming the promising utility of ortho-benzoquinone monohemiaminals.",
author = "Emi Saito and Yuri Matsumoto and Akihiko Nakamura and Yuki Namera and Masahisa Nakada",
note = "Funding Information: We acknowledge support of the Materials Characterization Central Laboratory, Waseda University, for characterization of new compounds. This work was financially supported in part by the Grant-in-Aid for Scientific Research on Innovative Areas 2707 Middle Molecular Strategy from MEXT and a Waseda University Grant for Special Research Projects. Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = feb,
day = "2",
doi = "10.1021/acs.orglett.7b03824",
language = "English",
volume = "20",
pages = "692--695",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "3",
}