Synthesis and self-assembling behavior of a porphyrin bearing multiple meso-conjugated barbiturates

Satoshi Arai, Toshiya Okamura, Shinji Takeoka

研究成果: Article査読

2 被引用数 (Scopus)

抄録

An efficient procedure through deprotection of 2,4,6-trimethoxypyrimidine derivative afforded porphyrinato zinc bearing multi-barbiturates acting as multiple hydrogen bonding sites at the meso positions. Addition of excess amphiphilic triaminopyrimidine derivative, as a complementary motif to the barbiturate, in an aqueous solution of porphyrin conjugated with multiple barbiturates at the meso positions resulted in precipitation. The cast film from the chloroform solution of the precipitate indicated the formation of a well-defined porphyrin assembly.

本文言語English
ページ(範囲)5177-5180
ページ数4
ジャーナルTetrahedron Letters
51
39
DOI
出版ステータスPublished - 2010 9 29

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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