Synthesis and structure of the first per-substituted anthracene host: Decakis(cyclopentylthio)anthracene

Christopher S. Frampton, William M. McGregor, David D. MacNicol, Paul R. Mallinson, Stuart J. Rowan, Raymond G. Plevey

研究成果: Article査読

5 被引用数 (Scopus)

抄録

The title compound, a novel host molecule, has been prepared both from mixtures of unsaturated fluorocarbons related to perfluoroperhydroanthracene and, in an extension of a remarkable new reaction, perfluoroperhydroanthracene itself. The 1,4-dioxane inclusion compound of this anthracene-based host is triclinic, space group PI, with a=11.826(l), b=15.297(1), c=20.280(l) Å, α=98.77(1), β = 99.85(1), and γ = 95.83(1)°, with two host, and ca. three 1,4-dioxane guest molecules per unit cell. The host molecule occupies a general position in the unit cell and its anthracene core is markedly non-planar; each of the three crystallographically independent six-membered rings possesses a shallow twist-boat conformation. The host's side-chain moieties display an asymmetrical conformational distribution of the abbabaabab type (a = above, b = below, mean core plane).

本文言語English
ページ(範囲)223-226
ページ数4
ジャーナルSupramolecular Chemistry
3
3
DOI
出版ステータスPublished - 1994
外部発表はい

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント 「Synthesis and structure of the first per-substituted anthracene host: Decakis(cyclopentylthio)anthracene」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル