Synthesis of chiral dendrimers with a hydrocarbon backbone and application to the catalytic enantioselective addition of dialkylzincs to aldehydes

Itaru Sato, Takanori Shibata, Koji Ohtake, Ryo Kodaka, Yutaka Hirokawa, Nobuaki Shirai, Kenso Soai

研究成果: Article査読

54 被引用数 (Scopus)

抄録

Chiral dendrimers with three or six β-amino alcohols on hyperbranched hydrocarbon chain-ends were synthesized. These macromolecules can act as chiral catalysts for the enantioselective addition of dialkylzincs to aldehydes. The corresponding secondary alcohols are obtained in high enantiomeric excess (up to 86% e.e.). (C) 2000 Elsevier Science Ltd.

本文言語English
ページ(範囲)3123-3126
ページ数4
ジャーナルTetrahedron Letters
41
17
DOI
出版ステータスPublished - 2000 4 22
外部発表はい

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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