Synthesis of conductive polymers having nitrogen atoms as donor atoms and analysis of complexation process for metal irons

Yuichi Iai; Koji Ikkanda; Ken Tanaka; Aritomo Yamaguchi; Kenichi Oyaizu; Makoto Yuasa

Synthesis of conductive polymers having nitrogen atoms as donor atoms and analysis of complexation process for metal irons

Yuichi Iai, Koji Ikkanda, Ken Tanaka, Aritomo Yamaguchi, Kenichi Oyaizu, Makoto Yuasa

研究成果: Paper › 査読

抄録

It was found that 3-pyridylthiophen formed a conductive thin film by electropolymerization. The polymer, which had nitrogen atoms as donor atoms, coordinated to cobalt(II) ion. It was demonstrated that the metal-polymer complex could be used as a cathode catalyst for fuel cells. The potential of oxygen reduction was very high (E_p ∼ 0.4 V vs SCE) for the catalyst prepared by refluxing pyrrole, cobalt, and carbon particles which were modified by polymerization of 3-pyridylthiophen and pyrrole.

本文言語	English
ページ数	1
出版ステータス	Published - 2005 12 1
外部発表	はい
イベント	54th SPSJ Annual Meeting 2005 - Yokohama, Japan 継続期間: 2005 5 25 → 2005 5 27

Conference

Conference	54th SPSJ Annual Meeting 2005
Country	Japan
City	Yokohama
Period	05/5/25 → 05/5/27

ASJC Scopus subject areas

Engineering(all)

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引用スタイル

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title = "Synthesis of conductive polymers having nitrogen atoms as donor atoms and analysis of complexation process for metal irons",

abstract = "It was found that 3-pyridylthiophen formed a conductive thin film by electropolymerization. The polymer, which had nitrogen atoms as donor atoms, coordinated to cobalt(II) ion. It was demonstrated that the metal-polymer complex could be used as a cathode catalyst for fuel cells. The potential of oxygen reduction was very high (Ep ∼ 0.4 V vs SCE) for the catalyst prepared by refluxing pyrrole, cobalt, and carbon particles which were modified by polymerization of 3-pyridylthiophen and pyrrole.",

keywords = "Electrocatalyst, Electropolymerization, Oxygen reduction, Poly(3-pyridylthiophen)",

author = "Yuichi Iai and Koji Ikkanda and Ken Tanaka and Aritomo Yamaguchi and Kenichi Oyaizu and Makoto Yuasa",

year = "2005",

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note = "54th SPSJ Annual Meeting 2005 ; Conference date: 25-05-2005 Through 27-05-2005",

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T1 - Synthesis of conductive polymers having nitrogen atoms as donor atoms and analysis of complexation process for metal irons

AU - Iai, Yuichi

AU - Ikkanda, Koji

AU - Tanaka, Ken

AU - Yamaguchi, Aritomo

AU - Oyaizu, Kenichi

AU - Yuasa, Makoto

PY - 2005/12/1

Y1 - 2005/12/1

N2 - It was found that 3-pyridylthiophen formed a conductive thin film by electropolymerization. The polymer, which had nitrogen atoms as donor atoms, coordinated to cobalt(II) ion. It was demonstrated that the metal-polymer complex could be used as a cathode catalyst for fuel cells. The potential of oxygen reduction was very high (Ep ∼ 0.4 V vs SCE) for the catalyst prepared by refluxing pyrrole, cobalt, and carbon particles which were modified by polymerization of 3-pyridylthiophen and pyrrole.

AB - It was found that 3-pyridylthiophen formed a conductive thin film by electropolymerization. The polymer, which had nitrogen atoms as donor atoms, coordinated to cobalt(II) ion. It was demonstrated that the metal-polymer complex could be used as a cathode catalyst for fuel cells. The potential of oxygen reduction was very high (Ep ∼ 0.4 V vs SCE) for the catalyst prepared by refluxing pyrrole, cobalt, and carbon particles which were modified by polymerization of 3-pyridylthiophen and pyrrole.

KW - Electrocatalyst

KW - Electropolymerization

KW - Oxygen reduction

KW - Poly(3-pyridylthiophen)

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M3 - Paper

AN - SCOPUS:33645641164

T2 - 54th SPSJ Annual Meeting 2005

Y2 - 25 May 2005 through 27 May 2005

ER -