It was found that 3-pyridylthiophen formed a conductive thin film by electropolymerization. The polymer, which had nitrogen atoms as donor atoms, coordinated to cobalt(II) ion. It was demonstrated that the metal-polymer complex could be used as a cathode catalyst for fuel cells. The potential of oxygen reduction was very high (Ep ∼ 0.4 V vs SCE) for the catalyst prepared by refluxing pyrrole, cobalt, and carbon particles which were modified by polymerization of 3-pyridylthiophen and pyrrole.
|出版ステータス||Published - 2005 12 1|
|イベント||54th SPSJ Annual Meeting 2005 - Yokohama, Japan|
継続期間: 2005 5 25 → 2005 5 27
|Conference||54th SPSJ Annual Meeting 2005|
|Period||05/5/25 → 05/5/27|
ASJC Scopus subject areas