Synthesis of Decaarylanthracene with Nine Different Substituents

研究成果: Article査読

2 被引用数 (Scopus)

抄録

A synthesis of decaarylanthracene with nine different substituents has been accomplished by a coupling/ring-transformation strategy. The oxidation of tetraarylthiophenes with four different substituents to the corresponding thiophene S-oxides and a [4 + 2] cycloaddition with a double benzyne precursor afforded a multiply arylated naphthalene derivative. Subsequently, the naphthalene derivative was converted into a naphthalyne, and then a [4 + 2] cycloaddition of another thiophene S-oxide provided decaarylanthracenes with nine different aryl groups.

本文言語English
ページ(範囲)15437-15448
ページ数12
ジャーナルJournal of Organic Chemistry
85
23
DOI
出版ステータスPublished - 2020 12 4

ASJC Scopus subject areas

  • 有機化学

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