Synthesis of Diazocine-containing poly(arylene ether sulfone)s for tailored mechanical and electrochemical performance

Takeo Suga, Sungsool Wi, Timothy E. Long

研究成果: Article査読

19 被引用数 (Scopus)

抄録

A series of poly(arylene ether sulfone) copolymers containing the diazocine unit (0, 20, 50, 80,100 mol %) were synthesized Via step-growth polymerization. Copolymer compositions exhibited number-average molecular weights exceeding 30 000 g/mol, and mechanically ductile films were obtained for all compositions.The random copolymers exhibited enhanced thermal stability (T d10%) 500-550 °C) and mechanical properties(tensile stress) 45-65 MPa), and the thermomechanical performance was predictable based on copolymer composition. A secondary transition in the dynamic mechanical analysis appeared at 28 °C, which was attributed to segmental motion of the bulky diazocine and biphenyl units. X-ray single crystallography and 1H NMR spectroscopy as a function of temperature revealed that the diazocine ring existed in the boat-shaped conformation. The effective dipolar couplings of site-specific 1 H- 13 C dipolar couplings in the aromatic rings were measured using DIPSHIFT solid state NMR spectroscopy at various temperatures. The experimental data indicated that the bulkier diazocine group experienced slower ring-flip motion than the smaller phenylene group. Cyclic voltammograms of diazocine-containing poly(arylene ether sulfone)s exhibited two reversible reduction peaks at -0.68 and -1.21 V under inert and basic conditions. UV spectra of the diazocine group in the reduced state indicated an extended π-electron structure, which supported the boat- to planar-conformational change (molecular actuation) Via redox reactions.

本文言語English
ページ(範囲)1526-1532
ページ数7
ジャーナルMacromolecules
42
5
DOI
出版ステータスPublished - 2009 3 10
外部発表はい

ASJC Scopus subject areas

  • 有機化学
  • ポリマーおよびプラスチック
  • 無機化学
  • 材料化学

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